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  • 1. Hytteborn, Julia K.
    et al.
    Temnerud, Johan
    SMHI, Research Department, Hydrology.
    Alexander, Richard B.
    Boyer, Elizabeth W.
    Futter, Martyn N.
    Froberg, Mats
    Dahne, Joel
    SMHI, Professional Services.
    Bishop, Kevin H.
    Patterns and predictability in the intra-annual organic carbon variability across the boreal and hemiboreal landscape2015In: Science of the Total Environment, ISSN 0048-9697, E-ISSN 1879-1026, Vol. 520, p. 260-269Article in journal (Refereed)
    Abstract [en]

    Factors affecting total organic carbon (TOC) concentrations in 215 watercourses across Sweden were investigated using parameter parsimonious regression approaches to explain spatial and temporal variabilities of the TOC water quality responses. We systematically quantified the effects of discharge, seasonality, and long-term trend as factors controlling intra-annual (among year) and inter-annual (within year) variabilities of TOC by evaluating the spatial variability in model coefficients and catchment characteristics (e.g. land cover, retention time, soil type). Catchment area (0.18-47,000 km(2)) and land cover types (forests, agriculture and alpine terrain) are typical for the boreal and hemiboreal zones across Fennoscandia. Watercourses had at least 6 years of monthly water quality observations between 1990 and 2010. Statistically significant models (p < 0.05) describing variation of TOC in streamflow were identified in 209 of 215 watercourses with a mean Nash-Sutcliffe efficiency index of 0.44. Increasing long-term trends were observed in 149 (70%) of the watercourses, and intra-annual variation in TOC far exceeded inter-annual variation. The average influences of the discharge and seasonality terms on intra-annual variations in daily TOC concentration were 1.4 and 1.3 mg l(-1) (13 and 12% of the mean annual TOC), respectively. The average increase in TOC was 0.17 mg l(-1) year(-1) (1.6% year(-1)). Multivariate regression with over 90 different catchment characteristics explained 21% of the spatial variation in the linear trend coefficient, less than 20% of the variation in the discharge coefficient and 73% of the spatial variation in mean TOC. Specific discharge, water residence time, the variance of daily precipitation, and lake area, explained 45% of the spatial variation in the amplitude of the TOC seasonality. Because the main drivers of temporal variability in TOC are seasonality and discharge, first-order estimates of the influences of climatic variability and change on TOC concentration should be predictable if the studied catchments continue to respond similarly. (C) 2015 Elsevier B.V. All rights reserved.

  • 2. Winterdahl, Mattias
    et al.
    Temnerud, Johan
    SMHI, Research Department, Hydrology.
    Futter, Martyn N.
    Lofgren, Stefan
    Moldan, Filip
    Bishop, Kevin
    Riparian Zone Influence on Stream Water Dissolved Organic Carbon Concentrations at the Swedish Integrated Monitoring Sites2011In: Ambio, ISSN 0044-7447, E-ISSN 1654-7209, Vol. 40, no 8, p. 920-930Article in journal (Refereed)
    Abstract [en]

    Short-term variability in stream water dissolved organic carbon (DOC) concentrations is controlled by hydrology, climate and atmospheric deposition. Using the Riparian flow-concentration Integration Model (RIM), we evaluated factors controlling stream water DOC in the Swedish Integrated Monitoring (IM) catchments by separating out hydrological effects on stream DOC dynamics. Model residuals were correlated with climate and deposition-related drivers. DOC was most strongly correlated to water flow in the northern catchment (Gammtratten). The southern Aneboda and Kindla catchments had pronounced seasonal DOC signals, which correlated weakly to flow. DOC concentrations at GAyenrdsjon increased, potentially in response to declining acid deposition. Soil temperature correlated strongly with model residuals at all sites. Incorporating soil temperature in RIM improved model performance substantially (20-62% lower median absolute error). According to the simulations, the RIM conceptualization of riparian processes explains between 36% (Kindla) and 61% (Aneboda) of the DOC dynamics at the IM sites.

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